Topics covered: Rutherford scattering, Bohr model, X-rays, de Broglie waves, nuclear physics, radioactivity, photoelectric effect.
1) Rutherford Scattering Experiment
- Helped understand the structure of the atom.
- Most α-particles pass undeflected or with small deflection.
- Few α-particles are deflected through large angles (> 90°).
2) Bohr Model of Hydrogen Atom
Postulates
- Electrons revolve in circular orbits under Coulomb attraction.
- Electrons emit or absorb energy only during transitions.
- Angular momentum is quantised: L = n·h / 2π
Key Formulae
Radius of nth orbit: rₙ = (n²h²) / (4π²mₑk e²) = n²a₀ Velocity of electron: vₙ = (ke²) / (nħ) Energy of nth orbit: Eₙ = −13.6 / n² eV
Energy of emitted photon:
hf = Ei − Ef
Rydberg Formula:
1/λ = R (1/nf² − 1/ni²) R = 1.097 × 10⁷ m⁻¹
3) X-rays
- Electromagnetic waves with wavelength range: 0.01 – 1 nm
- Continuous X-rays: Produced due to deceleration of electrons.
- Characteristic X-rays: Due to electronic transitions in atoms.
4) de Broglie (Matter) Waves
λ = h / p p = mv λ = h / mv If kinetic energy = E: λ = h / √(2mE)
For electrons accelerated by potential V:
λ (Å) = 12.27 / √V
Bohr Quantisation Condition:
L = mvr = nħ
5) Atomic Nucleus
Nuclear radius: R = R₀ A¹ᐟ³ R₀ ≈ 1.2 × 10⁻¹⁵ m
6) Radioactivity
- Radioactive decay is random and spontaneous.
- Independent of temperature, pressure, electric and magnetic fields.
- Decay rate ∝ number of undecayed nuclei.
Decay law: dN/dt = −λN N = N₀ e^(−λt)
Half-life:
T½ = 0.693 / λ
Mean life:
τ = 1 / λ
7) Photoelectric Effect
Emission of electrons from a metal surface when light of sufficient frequency falls on it.
Einstein’s equation: hν = φ₀ + Eₖ(max) Eₖ(max) = ½ mv² = eV₀
Important Observations
- Effect of intensity: Increases photoelectric current, KE unchanged.
- Effect of frequency: Increases KE, current unchanged.
- Threshold frequency (ν₀): Minimum frequency required.
- No time lag between incidence and emission.
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Last modified: December 14, 2025
