Topics covered: Rutherford scattering, Bohr model, X-rays, de Broglie waves, nuclear physics, radioactivity, photoelectric effect.


1) Rutherford Scattering Experiment

  • Helped understand the structure of the atom.
  • Most α-particles pass undeflected or with small deflection.
  • Few α-particles are deflected through large angles (> 90°).

2) Bohr Model of Hydrogen Atom

Postulates

  • Electrons revolve in circular orbits under Coulomb attraction.
  • Electrons emit or absorb energy only during transitions.
  • Angular momentum is quantised: L = n·h / 2π

Key Formulae

Radius of nth orbit:
rₙ = (n²h²) / (4π²mₑk e²) = n²a₀

Velocity of electron:
vₙ = (ke²) / (nħ)

Energy of nth orbit:
Eₙ = −13.6 / n²  eV
  

Energy of emitted photon:

hf = Ei − Ef
  

Rydberg Formula:

1/λ = R (1/nf² − 1/ni²)

R = 1.097 × 10⁷ m⁻¹
  

3) X-rays

  • Electromagnetic waves with wavelength range: 0.01 – 1 nm
  • Continuous X-rays: Produced due to deceleration of electrons.
  • Characteristic X-rays: Due to electronic transitions in atoms.

4) de Broglie (Matter) Waves

λ = h / p

p = mv

λ = h / mv

If kinetic energy = E:
λ = h / √(2mE)
  

For electrons accelerated by potential V:

λ (Å) = 12.27 / √V
  

Bohr Quantisation Condition:

L = mvr = nħ
  

5) Atomic Nucleus

Nuclear radius:
R = R₀ A¹ᐟ³

R₀ ≈ 1.2 × 10⁻¹⁵ m
  

6) Radioactivity

  • Radioactive decay is random and spontaneous.
  • Independent of temperature, pressure, electric and magnetic fields.
  • Decay rate ∝ number of undecayed nuclei.
Decay law:
dN/dt = −λN

N = N₀ e^(−λt)
  

Half-life:

T½ = 0.693 / λ
  

Mean life:

τ = 1 / λ
  

7) Photoelectric Effect

Emission of electrons from a metal surface when light of sufficient frequency falls on it.

Einstein’s equation:
hν = φ₀ + Eₖ(max)

Eₖ(max) = ½ mv² = eV₀
  

Important Observations

  • Effect of intensity: Increases photoelectric current, KE unchanged.
  • Effect of frequency: Increases KE, current unchanged.
  • Threshold frequency (ν₀): Minimum frequency required.
  • No time lag between incidence and emission.
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